王高凯 1,2,*张兴旺 1,2
作者单位
摘要
1 中国科学院半导体研究所, 半导体材料科学重点实验室, 北京 100083
2 中国科学院大学, 材料与光电研究中心, 北京 100049
二维超宽禁带半导体材料六方氮化硼(h-BN)具有绝缘性好、击穿场强高、热导率高, 以及良好的稳定性等特点, 且其原子级平整表面极少有悬挂键和电荷陷阱的存在, 使其有潜力成为二维电子器件的衬底和栅介质材料。实现h-BN应用的关键在于生长高质量的h-BN单晶薄膜, 本文详细介绍了在过渡金属衬底、绝缘介质衬底和半导体材料表面外延生长h-BN的方法及其研究进展。在具有催化活性的过渡金属衬底(铜、镍、铁、铂等)上可以外延得到高质量的二维h-BN, 而在绝缘介质或半导体材料衬底上直接生长h-BN单晶薄膜更具挑战性。蓝宝石以其良好的热稳定性和化学稳定性成为外延h-BN的首选衬底, 蓝宝石衬底上生长h-BN薄膜的方法主要有化学气相沉积、分子束外延、离子束溅射沉积、金属有机气相外延, 以及高温后退火等, 通过这些方法可以在蓝宝石衬底上外延得到h-BN单晶薄膜, 还可以集成到现有的一些III-V族化合物半导体的外延生长工艺之中, 为h-BN的大面积应用奠定基础。此外, 石墨烯、硅和锗等半导体材料衬底上生长h-BN单晶薄膜也是当前研究的一个热点, 这为基于h-BN的异质结制备及其应用提供了新的方向。
六方氮化硼 外延生长 薄膜 二维材料 宽禁带半导体 hexagonal boron nitride epitaxial growth thin film two-dimensional material wide band gap semiconductor 
人工晶体学报
2023, 52(5): 825
Author Affiliations
Abstract
1 Key Lab of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
2 School of Information Science and Technology, North China University of Technology, Beijing 100144, China
3 Faculty of Science, Beijing University of Technology, Beijing 100124, China
4 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
The behavior of H inβ-Ga2O3 is of substantial interest because it is a common residual impurity that is present inβ-Ga2O3, regardless of the synthesis methods. Herein, we report the influences of H-plasma exposure on the electric and optical properties of the heteroepitaxialβ-Ga2O3 thin films grown on sapphire substrates by chemical vapor deposition. The results indicate that the H incorporation leads to a significantly increased electrical conductivity, a greatly reduced defect-related photoluminescence emission, and a slightly enhanced transmittance, while it has little effect on the crystalline quality of theβ-Ga2O3 films. The significant changes in the electrical and optical properties ofβ-Ga2O3 may originate from the formation of shallow donor states and the passivation of the defects by the incorporated H. Temperature dependent electrical properties of the H-incorporatedβ-Ga2O3 films are also investigated, and the dominant scattering mechanisms at various temperatures are discussed.The behavior of H inβ-Ga2O3 is of substantial interest because it is a common residual impurity that is present inβ-Ga2O3, regardless of the synthesis methods. Herein, we report the influences of H-plasma exposure on the electric and optical properties of the heteroepitaxialβ-Ga2O3 thin films grown on sapphire substrates by chemical vapor deposition. The results indicate that the H incorporation leads to a significantly increased electrical conductivity, a greatly reduced defect-related photoluminescence emission, and a slightly enhanced transmittance, while it has little effect on the crystalline quality of theβ-Ga2O3 films. The significant changes in the electrical and optical properties ofβ-Ga2O3 may originate from the formation of shallow donor states and the passivation of the defects by the incorporated H. Temperature dependent electrical properties of the H-incorporatedβ-Ga2O3 films are also investigated, and the dominant scattering mechanisms at various temperatures are discussed.
Journal of Semiconductors
2022, 43(9): 092802
Author Affiliations
Abstract
Department of Electrical Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, USA
The exploration of quantum inspired symmetries in optical systems has spawned promising physics and provided fertile ground for developing devices exhibiting exotic functionalities. Founded on the anti-parity–time (APT) symmetry that is enabled by both spatial and temporal interplay between gain and loss, we demonstrate theoretically and numerically bi-color lasing in a single micro-ring resonator with spatiotemporal modulation along its azimuthal direction. In contrast to conventional multi-mode lasers that have mixed-frequency output, our laser exhibits stable, demultiplexed, tunable bi-color emission at different output ports. Our APT-symmetry-based laser may point out a new route for realizing compact on-chip coherent multi-color light sources.
Photonics Research
2021, 9(7): 07001280
作者单位
摘要
1 Physics Department, Zhejiang Normal University, Jinhua 321004, China
2 Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
3 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
inorganic perovskite solar cell (PSC) holetransport material (HTM) stability 
Frontiers of Optoelectronics
2020, 13(3): 265
Yang Zhao 1,2Fei Ma 1,2Feng Gao 1,2Zhigang Yin 1,2[ ... ]Jingbi You 1,2,*
Author Affiliations
Abstract
1 Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
2 College of Materials Science and Opto-electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
The record power conversion efficiency of small-area perovskite solar cells has impressively exceeded 25%. For commercial application, a large-area device is the necessary next step. Recently, significant progress has been achieved in fabricating efficient large-area perovskite solar cells. In this review, we will summarize recent achievements in large-area perovskite solar cells including the deposition methods as well as growth control of the large-area, high-quality perovskite layer and also the charge transport layer. Finally, we will give our insight into large-area perovskite solar cells.
Photonics Research
2020, 8(7): 070000A1
Yong Chen 1,2Yang Zhao 1,2Qiufeng Ye 1,2Zema Chu 1,2[ ... ]Jingbi You 1,2
Author Affiliations
Abstract
1 Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
2 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Although perovskite solar cells containing methylamine cation can show high power conversion efficiency, stability is a concern. Here, methylamine-free perovskite material CsxFA1–xPbI3 was synthesized by a one-step method. In addition, we incorporated smaller cadmium ions into mixed perovskite lattice to partially replace Pb ions to address the excessive internal strain in perovskite structure. We have found that the introduction of Cd can improve the crystallinity and the charge carrier lifetime of perovskite films. Consequently, a power conversion efficiency as high as 20.59% was achieved. More importantly, the devices retained 94% of their initial efficiency under 1200 h of continuous illumination.
Journal of Semiconductors
2019, 40(12): 122201
Author Affiliations
Abstract
1 Beijing Key Laboratory of New and Renewable Energy, North China Electric Power University, Beijing 102206, China
2 Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
3 National Engineering Research Center for Optoelectronic Devices, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
Forward-scattering efficiency (FSE) is first proposed when an Ag nanoparticle serves as the light-trapping structure for thin-film (TF) solar cells because the Ag nanoparticle’s light-trapping efficiency lies on the light-scattering direction of metal nanoparticles. Based on FSE analysis of Ag nanoparticles with radii of 53 and 88 nm, the forward-scattering spectra and light-trapping efficiencies are calculated. The contributions of dipole and quadrupole modes to light-trapping effect are also analyzed quantitatively. When the surface coverage of Ag nanoparticles is 5%, light-trapping efficiencies are 15.5% and 32.3%, respectively, for 53- and 88-nm Ag nanoparticles. Results indicate that the plasmon quadrupole mode resonance of Ag nanoparticles could further enhance the light-trapping effect for TF solar cells.
薄膜太阳电池 金属纳米颗粒 陷光效率 前向散射 290.4020 Mie theory 240.6680 Surface plasmons 350.6050 Solar energy 290.2558 Forward scattering 
Chinese Optics Letters
2011, 9(3): 032901

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